Ok - It's been mentioned already, but let me clarify...is this your first saltwater tank?
If so...please step back for a few days, read some posts here and take the time to enjoy the hobby. A lot of the questions you are asking can be answered simply by reading posts from other reefers.
Lights - the lights you purchased will work fine - you will want to replace the stock bulbs at some point - but most folks use them for 6-8 months first, and then replace them. There are many posts about what color bulbs to get, how long to run them, etc. So I wont answer that here.
Pumps - the genX pumps are a quality pump - you probably DO NOT need both running at the same time. Many folks only run a few hundred GPH through their sumps, since the bottleneck is the overflow capacity. As well, more flow through the sump makes for microbubbles in the main tank display - which takes away from the water clarity.
Various NextReef media chambers - the media chambers are valuable - I have never used NextReef, so I wont comment on them, I will only say that I use 2 chambers, each run off a manifold from the main pump, one for GFO (granular ferric oxide) to remove phosphate, and one for carbon. The carbon is changed every 2-3 weeks, the GFO changed every 4-6 weeks.
Koralia magnum pumps- these are in-tank pumps, to create flow. More pumps with higher GPH, reduces the need to use higher GPH return pumps...this saves you electricity in the long run. These pumps are NOT controllable! So, they are basically on or off. These are AC pumps - controllable pumps are DC and are more expensive, but are controllable.
The "wavemaker:" That is simply a device that powers the switches on/off. I would not use it with the Koralia as they will burn out quickly being cycled on/off at that rate. If you want to use them on a "wave maker." I'd heed the suggestion of another person above and get a controller (Neptune, profilux, reefkeeper, etc. all make reputable controllers). With the controller, you can program when particular outlets are on or off. For your koralia's for example, to create some random flow, you might turn on pumps a and b for 6 hours, then off, and switch with pumps c/d on/off for 6 hours. This would create a "tidal" change in the tank, and would allow the pumps to go on/off only a few times a day.
Plumbing - plan this out! Seriously..take some time, look at other tanks in this forum. Before each pump, please, please, please make sure that you include a union and a ball valve, so that you can service the pumps, without having to drain some of the tank water. Take a look at some of the sponsors (bulkreefsupply comes to mind) and look at their plumbing selection - for true union ball valves.
plumbing size - use as large of plumbing as possible- larger diameter plumbing reduces head pressure thereby allowing more water to travel - make sure that the overflow and drains can handle all the water from the pumps! I would use 2X sized drain as compared to return - so 1.5" drain to .75" return from the pump. also, calculate the head pressure, as suggested above, to get an idea of the amount you will be facing.
Skimmer: I have not used this skimmer, but it seems sufficient for your tank.
Sump: I'm glad that you got a larger sump - is this a plain 75g tank? If so, you will want to add some compartments in there so that the water level in the skimmer section stays constant, then a return section (water drops in this section - so you can add an auto-top-off to add fresh water to the tank to keep salinity stable), baffles - to reduce bubbles, etc... (check out melevsreef.com for some examples of how to build a sump - also a sponsor of this forum).
Wow...there are still lots of things to consider, so take a look at what I said, and take some time to read about the issues.