This I find this to be an interesting topic. I'd like to chime in with a question.
I do a water change about once a month, I shoot for about 20%. Now I don't always do it once a month, I admit sometimes I tend to forget too. I try to do the 20% once a month, due to the fact that just about every book or anyone you ask say's 20% once a month or 10% every two weeks. Never the less, their's a number located with a time frame. Which this thread leads me to the questions:
How did we come to that figure??
How did we come to the calculation of any given certain amount within any certain given time frame??
I understand the replenishing part. Calcium, Alk & Mag. I understand that certain chemical's are depleted/used buy coral and most of us strive to keep them at a certain level. By testing one would find how much of this is used, therefor how much to replace. Beings each system is unique like every human is. With that thought process how did we establish that each tank needs the same amount at the same time frame??
I'm not disputing the water change, just wondering I guess. With a 225g tank & and 100g sump, I'm about 300 total volume. So I should be doing about a 60g NSW change every month. I only do a 55g NSW change as that's the size of my drum.
But another issue brought up here was the fact that the skimmer doesn't pull only fresh water out. I recently had to run a very wet skimmate and noticed my SG dropped. I use a RHS-10ATC refractometer and use the 53.oms calibration fluid from American Marine Inc. Beings I'm a bubbling fool I have to calibrate it more often, I seem to bump the adjusting nob on the top and then well you know...it's off.
So in theory, through other means like skimmer's, testing, pruning of cheato/macroalgea's and my arms in the tank more than they should be

, even though it's a small amount I notice I have to top off sometimes with NSW just to keep the SG @ 1.026. I like to keep it a little higher than the recommend 1.023.
So is it just a generalization of a certain amount in a certain time frame that we are going by?? Just curious.
Stu.