The only way rain water would be safe is if you ran it through a RO/DI filter or distilled it.
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what does tds stand for?
If you catch it in a clean container the TDS will be low. Remember that TDS does not measure the presence of any neutral organic molecules from the smog / pollution type stuff. That is more the type of thing you are worried about. DI resin won't help with those things either.
When air pollutants combine with water in the atmosphere, a chemical reaction occurs that results in the production of sulfuric acid. Later, when clouds form over the high peaks, the precipitation falls as acid rain.
Even more acidic is the acid fog. Rime ice, clouds that have frozen on the trees, has been measured at a PH of 2.1 near the Mile High Swinging Bridge. For comparison, lemon juice measures a PH of 2.5 and battery acid measures a PH of 1.