Hi
Dont worry about the null plug reading, i will post here in a seperate post the calibration instructions for you.
As for dropping reading with a Redox probe when new - This is 100% normal, what is hapening is the probe is bedding in, it can take up to one week for a redox probe to stabilise, after that i will read fine. Just leave it in the system and allow it to settle do not keep playing with it, otherwise it will never settle.