A couple of things have got to be happening......
-Wedge pipe is more than 3/4 closed, and you just can't tell, thus running a much higher water level to get the skimmer to skim (you have no bioload in the tank, the skimmer won't work).
-Sump level is varying somewhat, even 1/4" - 1/2" will make a difference.
-Something is getting in the water to cause the reaction
There has to be a reason for the oveflow. It's physically impossible for the skimmer to just overflow for no reason (the pump can not speed up and slow down). I would recommend going back and checking these things. In all honesty, you have essentially no bioload on the system. This tells me that you need to run the water level really high into the neck to try and get the skimmer to work. 3/4 closed in 8" of water would not get the water level that high, which tells me it's probably closed more than 3/4. Having said all this, it's probably running 3" or so from the top of the neck, which is entirely too high.
Let me know what you find out.
Thanks,
Jeremy