some have had success sandwiching aquamend between thick beads of locktite super glue. I've not tried that method but it makes sense. I've found the aquamend helps in that it takes the shape of how the two rocks meet and so makes it a bit more stable, but it doesn't really adhere. the super glue does, but needs more surface area to bind. the aquamend provides that. both are safe for your tank, but I'd do as much of it as possible before adding fish and inverts. what I have done with success is to drill holes in the rock once I've determined how I want them placed and attach by way of acrylic rod. you can safely construct overhangs that way. as long as you wet the rock with saltwater from time to time you won't get much in the way of die-off