Andy,
The 180 really have just 1 advantage over a 100mm macro lens. It has a minimum focusing distance of 46cm from the sensor plane. The length of the lens is 18.2cm, meaning that it has a "min. focusing distance" of 27.8cm from the front lens element.
I mainly shoot insects, so the 180 help me keep my distance as not to scare the critters away.
Keep in mind that the 180 is bulky and heavy (965g) and thus unless you have a specific need for it, I would stick with the 100. In fact, I don't feel the 180 and 100 are mutually exclusive. I would prefer to shoot with a 100 if I am just shooting still life or even aquarium.
Hope that helps a little.