Why is this bad? How do you know?
This is going back a few pages, a question in response to my statement that if the pellets don't tumble they stick together, and may form a detritus trap and go anaerobic as a result of their impermeability:
Short answer is I don't know, but have some ideas. Anaerobic zones aren't necessarily bad - in fact they are good in that they perform often "complementary" or unique functions to aerobic zones. Sediments are typically anaerobic an inch or two below the surface zone in quiescent (low energy) locations. Even in our tanks, for those that have relatively large grain size aragonitic sands (i.e. permeable material) as a deep sand bed, anaerobic zones set up over time (thanks in large part to the accumulation of smaller particle size detritus which fills pore spaces in the sand), anaerobic zones build up. It is not until these anaerobic zones are disturbed through stirring of the sand are there problems in the water column due to release of reduced substance such as sulfides (though aged deep sand beds, like mine that I removed a couple of years ago, also seem to cause problems due to the production and release of nutrients/reduced compounds/nasties to the water column).
It's a little different for biodegradable polymers however. The detritus in these anaerobic clumps of pellets degrade and release nasties to the water column, but the polymer itself is also likely broken down to intermediate incomplete degradation compounds, which is very different from the aerobic pathways. These intermediates may then be released to the water column where they may cause problems directly, or indirectly such as being deposited on glass, rock etc., where they may then serve as a nutrient sink. The great advantage of bio pellets is purportedly the immobilized nature of the carbon source, where the bacteria can then be localized, fed to the protein skimmer, and nutrients exported. Perhaps this is the reason cyano or other bacterial blooms result in some tanks where the carbon source is disseminated throughout the tank. While I have no direct evidence that this is what happens (and there are many other possibilities), anecdotal accounts seem to support this.
Also, in general, hydrocarbons (which biopellet polymers can be considered), are degraded to carbon dioxide and water in aerobic systems, but are created in anaerobic systems (fossil fuels); in other words, very different biochemistry is taking place. The advantage of biopellets is realized in aerobic settings where the polymer provides a carbon source in our carbon-limited systems, to keep up with N and P which are all too plentiful in our little closed systems. The carbon in the polymer is released and/or broken down and assimilated by the bacteria, which also scrub the troublesome N and P from the water column to create biomass (or use it as an energy source).
But in the end, you're right, I don't really know, but bio pellets seem to be the best thing for my tank since GFO (and much better, at least for me, since they promote biological uptake of nutrients and are easier to prevent overstripping the water of what is needed for coral growth like the purely chemical-based removal actions of GFO, which also binds-out other compounds/elements besides phosphate).