When I switched over I did so one bulb at a time so for a week I had the XM in one fixture and EVC in the other. It wasn't so much that the EVC looked much bluer as it was that the XM looked a touch whiter. Of course, MH bulbs need a little burn in time so comparing a fresh EVC with a older XM directly isn't entirely valid.
I use a Sunlight Supply BlueWave dual magnetic ballast.
When I initially decided to go with 20,000K bulbs I was a bit concerned that my tank would look too blue, but after seeing the awesome colors that resulted I am sold on them.