RODI won't do that unless there's no aeration. Your Apex probes need to be recalibrated. Get new calibration fluids if they're more than 6 months old.
My gut feeling is that it's not ph, but I'm out of my league a bit with 1000 gallon fish only system. I look forward to the lab test results. I'll be very surprised if they don't show something.
+1 on re-calibrating your PH probes. I have 2 PH probes with my APEX and as time goes on the PH keeps creeping higher and higher. I have seen my probes tell me over 9 and when re-calibrated they are back to a normal level. Hanna also sells a PH tester for about $40. I use that when I am not confident the PH probes through the APEX are giving me an accurate reading. Do you have any other PH testing kits? It is never a bad thing to have some cheap kits around to double check. If all of these sources are saying 8.5 then you may have a problem you need to look into.
Keeping a refractometer or even a cheapo swing-arm hydrometer on hand can tell you pretty quickly when your pH probes are going out of whack.
Dave.M
Just a thought, I know you have you have your sump in your garage. Do you warm up your cars in the garage for extended periods of time? I know I warm up my exotics at least 10 minutes before I take them out. Maybe the fumes from the cars are getting into the tank?
My cousin had a rabbit he kept in his garage decades ago and one day it died, presumably from his mom warming up the car in the garage even with the garage door open.
Have sent in water samples to Aqua Medic. Will get results in the next few days
Ill post the results from the Aqua Medic Testing
I'm 10 minutes from Aqua Medic, want me to stop in and get your results?! :spin3: