Since you had a T5/LED combo already, I feel that your corals will be better off than other tanks. In terms of PAR, your ATI unit will be similar, but with more light punched down towards the bottom and certainly a far greater coverage/area of high PAR. Ie FAR less shadows etc, these areas will be filled with light.
Start off with JUST the T5's to burn them in for a week anyway. Let the T5's run around 6-7 hours for 7 days. Then work the LED's in slowly until you are happy with the overall look.
I run my LED's and T5's at 100% for around 3.5 hours I think. And both are ramping up or down either side of that; I think I am running a 10 hour light cycle. Obviously if I didnt have dimmable LED's and T5's I wouldnt run such a long light cycle.
As for the T5 combo: FOR SPS Dominated
Front: This is a nice combo which I know works.
ATI Blue+
ATI Blue+
ATI Purple+
ATI Blue+
--LED's--
ATI Coral+
ATI Blue+
ATI Purple+
ATI Blue+
Or: For a lightly brighter look
ATI Blue+
ATI Blue+
ATI Coral+
ATI Blue+
--LED's--
ATI Purple+
ATI Blue+
ATI Coral+
ATI Blue+
Or: More "whiter" than a above.
ATI Blue+
ATI Blue+
ATI Purple+
ATI Blue+
--LED's--
KZ NEWGEN 14K+
ATI Blue+
ATI Purple+
ATI Blue+
Remember you have the LED clusters/channel to further adjust the appearance of the overall look.
For an LPS/Zoa dominated tank:
Front
ATI Blue+
ATI Actinic
ATI Purple+
ATI Blue+
--LED's--
ATI Blue+
ATI Actinic+
ATI Purple+
ATI Blue+
And then use as much Royal Blue as your corals can deal with, add a good measure of Blue and a bit of White light from the LED's. That will have the LPS/Zoas popping!