So you had coralline growing at one point and then it stopped, or the coralline that came on your rock's is starting to die off ?
Low alkalinity can cause any calcifying organism to suffer. My advice is to just maintain alkalinity and calcium. Don't bother with the purple up because it contain's some thing's you may not want to be dosing to your tank.
IMO just keeping calcium alkalinity and magnesium in line is enough for coralline to thrive. Ph help's too, you may want to use the baked baking soda to raise your alk because that will help to keep your ph up wich increases calcification.
As far as chaeto, I've had the same problem. Some tank's it grow's great and some it doesn't. I recently swapped out my chaeto in favor of some grape caulerpa. I have not had much growth of that yet as well, but the ph is already a bit higher than it was with the chaeto. I think it would be worth trying to dose iron first though, and see if anything changes before you try something different.
I hope that help's.