I've used both, for years before NOPX came out, in a combination similar to NOPX levels. . Vodka and vinegar are very close ,The ethanol in the vodka oxidizes to acetic acid
5% acetic acid vinegar is 95% water, 80 proof vodka is only 40% water. So,: it takes about 1/8 th the dose with vodka to equal a given vinegar dose.
Vodka is easy to dose all at once ( bolus dosing); it does not cause precipitous downward pH spikes .Since it is less dilute than vinegar it may be more difficult to dose via a timed doser since the amounts needed are very small but there really is no need to spread it out.
Vinegar needs to be dosed in small amounts at a time so timed dosing is a must with the amount usually needed. Unlike the ethanol in vodka , the acetic acid in vinegar dumps a bunch of CO2 when it hits the water .
In the end the acetic acid adds back to the pH and the overall effects on pH for the vodka and the vinegar are the same in terms of a lowering it but at the beginning the vinegar can drop it precipitously and the vodka doesn't.