hit the outside with primer and then a nice bead of glue around the circumference of the joint. If you can do the same from the inside of the valve you stand a better chance of it not leaking.
Next time make sure both pieces the joint are primed past the depth they are inserted too. Glue the pipe or whatever is the "male" piece first and then the female part. depending on the size of the glue applicator you may have to redip to get more glue for the female, but you don't want the female side full of glue, just enough to fully wet the surface and soften it a bit. When you insert the male in it should have enough glue to push a ~1/8" bead of glue up at the top of the female. Turn the assembly 90* and hold with pressure to keep the pieces from pushing apart. Wipe the joint of excess glue and enjoy the little high you're on for a few minutes before proceeding to the next piece.