hoping that removing the Bio Balls from my wet dry filter was the right move, had the majority situated below the water line,(I think they behave like live rock like that) and some were above the water line being dripped upon by the water flow. i am in the process of turning my tank from a FOWLR to a reef tank. wanted to help get my Nitrates down. I do have 120 + pounds of live rock in the tank itself.
Nitrate control is always an issue. Although bioballs are the favorite to blame, they are not always responsible. I have bioballs in my FOWLER and giant Biowheels in my reef tank, and my ntrates are 0 in both tanks with no algae issues for several years. Regardless, you have taken the bioballs out, so now the question is how to control your nitrates.
120 lbs live rock in a 180 gal sounds adequate, especially if they are the porous type. Make sure your rockscape is such that water flows around and within the rockscape to maximize filtration, avoid detritus.
You'll need adequate total flow. Depending on what coral you like to keep, your total flow should be from 20X to 50X your tank volume. As an example, my 150 SPS dominant mixed reef has a total of 7,500GPH or 50X. I would suggest 30X or a total of 5,400GPH for you as a start through a combination of powerheads and return pump, and make sure it is either random or chaotic. What is your current total flow?
You'll need a bigger skimmer, one that is rated for at least 300 gallons. The one you have is definitely too small. If your sump is too small, consider a HOB skimmer, an external skimmer, or a bigger sump.
Water changes have been the time honored way to control water parameters. Do it more frequently if the parameters are off, less often if things are stable and doing well. How often do you do water changes?
That's all I can think of for now. Hope it helps!