Randy can you explain this for us laymen? Does this mean alkalinity doesn't show up until the compound is broke down? If this is the case then maybe VC is available longer then suspected?
Sure.
Like acetate from vinegar (from an article linked earlier in the thread), there is no carbonate and bicarbonate added instantly. There is some amount of contribution to total alkalinity as the organic itself (ascorbate or acetate) will be detected in a total alkalinity test, hence adding some alkalinity. Then later when the organic is fully metabolized to CO2, H2O and HCO3- , there is a direct contribution to bicarbonate alkalinity from the HCO3-.
I've not worked out the exact chemical reaction for ascorbate, but for acetate it is:
(4) 2 O2 + CH3COO- ==> H2O + 2 CO2 + OH- = H2O + CO2 + HCO3-
which is from:
What is Alkalinity
http://www.advancedaquarist.com/2002/2/chemistry
Sure.
Like acetate from vinegar (from an article linked earlier in the thread), there is no carbonate and bicarbonate added instantly. There is some amount of contribution to total alkalinity as the organic itself (ascorbate or acetate) will be detected in a total alkalinity test, hence adding some alkalinity. Then later when the organic is fully metabolized to CO2, H2O and HCO3- , there is a direct contribution to bicarbonate alkalinity from the HCO3-.
I've not worked out the exact chemical reaction for ascorbate, but for acetate it is:
(4) 2 O2 + CH3COO- ==> H2O + 2 CO2 + OH- = H2O + CO2 + HCO3-
which is from:
What is Alkalinity
http://www.advancedaquarist.com/2002/2/chemistry