1) make sure your right-angle bracket is actually 90 degrees
2) clean bonding surfaces with denatured alcohol on a clean cotton cloth (like an old white t-shirt, they make bags of rags out of this material) EDIT: and blow off with compressed or canned air, and don't touch these surfaces again (with fingers or anything that would make them not clean)
3) attach your vertical panel to the right-angle bracket with both pieces fit together in their "final" position (i.e. where they will be once the pins are pulled).
4) at this point, do any shimming needed to tighten up the joint (into it's "final" position)
5) now, insert the pins, shim additionally if needed (should be very minor at this point) and blow out the joint with canned air
6) run solvent
7) pull pins after the soak time
8) make sure the joint is aligned at the ends
9) once the joint is starting to firm up (after about a minute or so) then momentarily loosen the clamps while very gently applying pressure to the top edge (pushing down on the joint, essentially). Gently, as in don't smash it together, you just don't want the vertical panel to move/fall sideways, let the weight of the panel do the work (that's all you need)
10) maybe add a small weight to the horizontal part of the 90 degree bracket
What the last couple steps do is allow the top piece to settle in a bit, as a very tiny fraction of (micrometers) of material is dissolved, and you want to close this tiny gap to prevent air intrusion along the joint (it's like the extra 1% towards perfection). It also prevent the 90 degree bracket from "suspending" the vertical panel up and allowing the gap to form, in the case where you made a goof on one of the setup steps, etc...you won't get much more squish-out when loosening the clamps, or rather, you shouldn't
Regarding the last pin pulling thing, yes that is totally expected. Pulling the last pin will result in final settling of the joint and this is where you see the squish-out. The syrupy stuff is dissolved acrylic from both sides (which creates the micrometer-gap that you account for my loosening the clamps)
HTH
Bud