alwest45,
In my writing so far above, I termed dwell time as the time it takes for a bubble to rise from bottom to top, and contact time as the time the water spends inside the skimmer. So 'B', according to your question. The amount of time that the water spends in the skimmer matters somehow... the proof is in the puddin'... but there are theories.
1.Perhaps the dwell time can be interchanged with contact time (as in, they are the same)... the time it takes for one protein to get attracted to a bubble might be cumulative (the protein doesnt need to have 120seconds with one bubble but could be many)...in which case this is true. Otherwise, if they are not the same, it stilll suggests that the harder to capture proteins are still being drawn upwards in the skimmer, even if they are not extracted right away. In which case, they would eventually end up in the foam head where the remainder of the ideal 120second dwell time can be achieved. More throughput would mean there is a higher turnover, meaning less time with each protein.
2. Perhaps dwell time can not be interchanged 1:1 with contact time, but perhaps more contact can make up for dwell time... like a 4:1 ratio or something. So the lower throughput of a recirc skimmer would mean more contact time.
3. The lower throughput could raise the ORP more... causing better skimming. A higher throughput would mean the incoming fresh tank water would lower the ORP, and it would take that much more air to raise the ORP.
4. The countercurrent nature of recirc skimmers means fresh water enters at the top, and has to travel through the whole height of the skimmer before it exits the bottom. Single pass skimmers have the water and air enter near the bottom, just inches from the outlet. The water can travel 6" and exit, not like a recirc skimmer.
As for the theory, so far, the attraction of proteins that chemists describe doesnt take much of the physical account of how the two travel together. What, the bubble is moving, so does a protein just hang around the top waiting for the bubble to reach the right age before latching on and going out the top?
From what I remember, proteins naturally build up in the top layers of the aquarium water... the proteins and oils are less dense than saltwater. So all in all, it would be reasonable to suggest that a protein could be dragged up to the top, knocked off the bubble, but still remain in the top areas of the skimmer. The proteins have to travel with the bubble to some extent... dont they? I mean, the interaction of the air and bubbles has been suggested to be a mutually dependent variable, neither the air nor the water's time is independent... its the interaction between the two.