Alkalinity plays a more significant role in pH regulation than does calcium (of course the two work in tandem -- ocean water is a nearly saturated calcium carbonate/bicarbonate solution, literally "liquid rock").
The only "real way" to do this is by testing your water. Get some high-quality test kits, keep your calcium at about 350+/-50 ppm, and your alkalinity at about 3.5 +/- 0.5 meq/l (I forgot what that is in dKH -- 9-11?). I dose daily with B-Ionic (about 1.5x the recommended "starter dose") and my water parameters have remained "excellent", with the pH between 8.1 and 8.3.
Your calcium/alkalinity utilization will depend drastically on what's in your tank. Obviously SPS and aggressive LPS corals will suck up a lot more than sand and a little rock, or a few mushrooms.
Have fun,
Dan