So the ONLY thing that I did that was out of the ordinary was put in two good size pieces of live rock from the LFS. They had received, what they told me was some Walt Smith cultured live rock, the day before. it was ridiculously clean and VERY purple. So purple that it made my normal purple rock look almost brown, two weeks later I had the acro problems and the color of the coralin on the new rocks has faded to the a dull redish/purple color like in Walt's pictures.
Another thought with this, is that was the purple part of the rock (i.e. a dye) or actual fantastic/bright coralline that was out-competed by your tank's own coralline. If the first one, then maybe the rock wasn't fully cured, and while it didn't peak your pH enough for you to notice (I assume you're running 24/7 pH monitoring) due to water volume or something, it did spike the alkalinity, which may not have been picked up by an old test kit. Or it was such a short period of time before it was used by growth or precipitated that you didn't test during that exact period of time that it spiked so you didn't see it?
Dunno, conspiracies abound, but your new rock pieces just made me think about that, since I know DIY liverock has a pretty decent curing phase that it has to go through. And most importantly, I just hope the worst is over and wish your tank a speedy recovery!