An update for posterity's sake.
So the gyrations I went through before helped for a while, but slowly pH started spiraling down again, getting back down to 7.65 or lower sometimes. So I added a kalk reactor (Avast Marine, nice unit), run through the top off. The kalk reactor does marvels for pH (easy to keep over 8.0), but has 2 issues for me: it spikes alk pretty quickly (and I vodka dose, so need to keep it below around 9.0), and I'm rate limited by evaporation.
So I settled on running the ATO through kalk only at night, letting evaporation during the day "save up" so it could be leveraged at night. This helped quite a bit with pH at night, but left me in the odd position of having pH during the day run lower than pH at night, sometimes dipping down to 7.7.
I finally looked at the effluent coming out of the Dastaco calcium reactor...and pH was 5.4. This explains a lot, since the Dastaco emits a decent amount of effluent. Dumping it directly into the sump dragged pH down enough to cause me issues (colony STN's overnight, etc.).
I set up an "effluent collector" bucket, and aerated it as a test. First bucket was small, only about a gallon, and aeration while the Dastaco was off was quick and effective (getting effluent pH up to over 8.1), but when the reactor was running the bucket o' effluent pH dropped to around 6.3 again.
So I finally set up a 5 gallon bucket, with a kick *** air disc and pump. That did the trick: effluent pH only gets down to around 7.5 during the day while the CA reactor is running, and using the kalk at night keeps tank pH between 7.8 and 8.0 all day. The only downside is that the effluent bucket is gravity driven, so I have a 5 gallon bucket mounted to the side of my house now.
So a couple lessons learned (by me; a lot of you probably already knew this):
- The Dastaco is a great CA reactor for larger tanks, but emits a lot of reeeeeally low pH effluent that can cause issues even on a 400G tank. Didn't have this pH issue on my old 240G, using a standard bubble CA reactor (but I still wouldn't give up the Dastaco).
- A kalk reactor works really well for pH raises, but can be rate limited by your evaporation
- Having to mount a 5G bucket to the side of your house is much easier if you're already divorced.