When I was setting up my Kalk reactor, I turned the feed pump on manual control "ON" with my AquaController and forgot about it. Duh! :rolleye1: Luckily I caught it very quickly but it had raised my PH to 9.0 within about 20 minutes.
Here are some things I have done to my set up to avoid similar situations as yours. They are pretty simple and cheap.
First off, my absolute favorite piece of equipment now is my AquaController Jr. As 8BALL_99 mentioned, you can set alarms, turn things off or on when parameters go too high or too low, etc, etc. The possibilities are ALMOST endless. If you dont have one, I highly suggest it. I think you can still get the Jr for under $300 with an 8 way direct connect. This will control your CA reactor, Kalk reactor, lights, heater, etc, and if you ever decide to upgrade to the II, Pro, III, etc, all you have to replace is the brain, not all the components. Enough said, I LOVE mine and will never get rid of it or some other kind of computer control.
As for the auto top off. Is your RO unit directly connected to the sump with a float valve? The big black ones that mechanically pressurize the unit and shut off the water supply? If so, you can add another one of those valves to your SW make up container and split the RO product line with a "T" connector going to SW make up container. This way, if the sump valve is open, it will fill the sump AND the reservoir at the same time. When the reservoir is full, it wont overflow and you will still be able to have make up water going to the sump. Then you wont have the problem of having to add 4+ gallons of lime water at once.
My top off system is fairly elaborate to explain. Its more simple in theory. Ill try for the short, short version. I have a SW make bucket and a FW holding bucket next to each other. They both have shut off valves in them and are Td off of the product line from my RO unit. I can cut off the SW make up if Im not using it via a ball valve. In order to avoid cycling my RO unit on and off all day, I have a solenoid valve on the product side connected to a multi-day digital timer which turns it on only 3 times a week. On top of the FW reservoir, I have 2 Aqualifter Vacuum pumps. One is connected to a float "switch" in the sump and provides the main evaporation top off for the tank. The second is connected to a timer on the AC Jr which runs fresh water through the Kalk reactor and into the sump every 30 minutes for 1 minute at a time. I do all this so that when the evaporation rate changes, the amount of lime water being added to the tank will not change. That will always stay constant. I also avoid situations like yours in case a large amount of water needs to be replaced at one time.
Sorry for being so long winded. I hope this helps. Let me know if you have any questions. I think your tank will be fine but it may take a few weeks or longer to get back to normal.
Good Luck and keep us posted.