One thing to look for is whether it's drilled (has overflows) or not. If it's not drilled, check to see if it's tempered glass on the back and/or bottom. Can't drill tempered. Also check the seams from the outside. There should be no bubbles (or only a few very small ones) in the silicone between the glass panels.
If you choose not to go with the 75 you're looking at, and are fixed with the 48" length, I'd second the 120 gallon suggestion. To my eye, there needs to be a balance between length, width and height. The 24 high by 24 deep just looks right, up to about 8' long. 8'+ tanks just seem too skinny if less than 30" high and 30" deep.
Either way, post up some pics when you get something set up.