Calling out all Chemists!!!!

i looked up msds of this glue and there is tetrahydrofuran 30-45% in it.
how bad is this stuff? and after being in use for about 1 yr will it still be an issue?

MSDS:
CAS # Component Percent
109-99-9 Tetrahydrofuran 30-45
108-94-1 Cyclohexanone 10-20
67-64-1 Acetone 10-20
78-93-3 Methyl ethyl ketone 8-18
9002-86-2 PVC (Chloroethylene, polymer) 8-15
68648-82-8 Ethene, chloro-, homopolymer, chlorinated 3-7
112945-52-5 Silica, amorphous, fumed, crystalline-free 1-5

NOTE:Can be used for potable water, pressure pipe and drain, waste and vent piping



It is highly volatile and gone within minutes if not seconds. Same for the other solvents listed. They're designed to be able to use for potable water shortly after gluing.
 
What about electricity? Some new device or old worn component? The silent killer. Especially with clams dying the tank must have a unique mechanism of cell death. You have ruled out many known toxins.
 
I had major issues with a sulfur denitrator. Any rotten egg smell? Do you test for Hydrogen Sulfide? Does it drive bacterial cloudiness?
 
In the test report, What does all the "ND" represent?

I have had it where electrical current in a tank causes electrolysis to take place. This causes Sodium hypochlorite to be produced.
 
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ND means not detected, or below their testing limits. I'll try to take a look at all the numbers in a bit.
 
My suspects would be:

Metal or another toxin from somewhere;perhaps the reactor media is releasing some as it dissolves. It takes very little to harm inverts including corals, much less than might show blue on a polyfilter; some have hadmetal contamination issues with Kent reef carbon as well. I doubt a quality manufacturer would use non reeef safe silicone.

The sulfur denitrator with nitrate at 0 might be dumping some hydrogen sulfide into the tank. I'd probably run the effluent through some gfo to help quickly oxidize any that might be there. That worked or me years ago when I did it based on tip from Randy Farley. You'd probably get a whiff of the distinctive sewer gs smell near the effluent exit if it was anoxic(0 nitrate and 0 oxygen) and making hydrogen sulfide.

I'd take a hard look at specific gravity to be sure of my levels and to hold it a bit more steady. Same for alk.
 
I would disconnect the sulfur denitrator and see what happens. I have always kept things very simple and relying on only live rock, protein skimming for filtration and calcium reactor for calcium alkalinity, limited occasional use of carbon and nothing else. Water changes 10-15 % a month.

Make sure your RO/DI system is working properly and removing chloramines if present in your source water. Use a reputable source of media in the calcium reactor.
 
most everyone has blamed the sulfur denitrator i will take it off line to see. chloramines i have not tested for. any recommendation on kits?
 
If the tank is reading zero for ammonia, then chloramine is unlikely to be the problem. You could try the Hach test kit for chlorine, though. I think it'll be okay in saltwater, but you might want to check.
 
most everyone has blamed the sulfur denitrator i will take it off line to see. chloramines i have not tested for. any recommendation on kits?
Not aware of any chloramine tests but if you maintain your RO/DI system properly there should be no concerns.
 
Not aware of any chloramine tests but if you maintain your RO/DI system properly there should be no concerns.

ro/di unit is brand new from BRS made for chloramines. tds in before DI is 0 and out after DI is 0. ammonia readings are always 0.
 
Do you have children that could be playing with something, sticking their hands or toys in there, something like that? Spouse using cleaning supplies or insecticides near the tank?
 
Do you have children that could be playing with something, sticking their hands or toys in there, something like that? Spouse using cleaning supplies or insecticides near the tank?

no kids no wife. my tank is in the garage which i hardly ever use cars sit outside 99% of the time.
 
Since your fish are OK, I suspect the LEDs. Maybe you have some bad ones throwing out some weird spectrum. I would go back to my MHs and try some sps or something that has been going fast.

It really could be a small thing. I had a tank crash years ago. It was FO and everything started dying. I replaced a few and they died. I then tore everything out and guess what. Sitting half buried in the sand if the refugium was a penny. Completely green.

Did you replace your substrate when you changed tanks? The old one could be messed up with the move or the new could be contaminated. I would pull it out.

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Since your fish are OK, I suspect the LEDs. Maybe you have some bad ones throwing out some weird spectrum. I would go back to my MHs and try some sps or something that has been going fast.

It really could be a small thing. I had a tank crash years ago. It was FO and everything started dying. I replaced a few and they died. I then tore everything out and guess what. Sitting half buried in the sand if the refugium was a penny. Completely green.

Did you replace your substrate when you changed tanks? The old one could be messed up with the move or the new could be contaminated. I would pull it out.

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Led were sols first then vega but cant be ruled out. i am leaning towards sulfur denitrator which had media 3 yrs old and tons of crap buildup in it. i have a feeling it the media was breaking down and maybe causing some toxic stuff. i cleaned it and replaced it with fresh media. lets see what happens.
 
Sometimes I think it is possible to get a bad batch of media. Recently I had several corals that were shrinking and a frogspawn lost one branch. I couldn’t figure out what I was doing wrong, I was keeping all parameters steady and never failed to do weekly water changes. Finally I took out 2 bags of chemi pure elite (carbon/gfo mixture) that I had in my sump and didn’t replace them because I wanted to see what would happen. After that, it seems with each water change the corals are looking better and better. So was this a bad batch of chemi pure elite? No, I wasn’t using too much, I was actually using one bag less then they recommend for my size tank.
 
true, it could be any of the above mentioned. i do run carbon and have seen bunch of bad batch reports on RC and GFO as well. i will replace GFO with new media and Carbon with a new source as well. sulfur denitrator's media is already replaced. i am not running anything else other than those 2 media's except cal reactor media which the unit itself is brand new and problem is pre-existing.
 
In post 1 you said you "cannot keep any corals happy more than few weeks."

In post 12 you said "the fish and inverts are perfectly fine and thriving. only inverts i kill are anemones and clams"

?????

Assuming the problem is with corals, the only thing that jumps out at me is the Phosban reactor. FWIW, BRS recommends 2.65 cups of GFO per 85 gallons. If you're using a single Phosban reactor for a tank your size, you may not be using enough GFO. Have you tested for phosphates? Also are you using GAC? If not, I'd recommend another reactor for GAC. FWIW, Boomer recommends a cup of GAC per 100 gals.
 
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