tripstank, if you can minimize surging from the overflow, than a direct hookup will give you better skimmer performance. However, if your plumbing setup allows for surging, the performance will suffer, since the skimmer water level will be constantly changing.
There are a lot of threads in the Deltec USA forum about how to hook a skimmer up to an overflow (this is the way Deltec recommends). Your other option is to put a "bucket" of some sort in your sump that the overflow water drains in to before going into the sump. Put a small skimmer feed pump in the bucket, and you have almost the same raw water with steadier flow and less plumbing work.