Lanthanum chloride

Tested my PO4 this am after my 2nd dose of LaCl3 and it is now .03. That's after 2 diluted doses of LaCl3 at 2.5 ml / L for 150 gallons. I'm still quite impressed. In 3 days it brought my PO4 down to .03 from .49 after 2 doses. I'll keep an eye on it, because I'm sure I'll have some PO4 leaching from my LR, but I don't mind another dose or two. The biopellets and GFO should help as well.
 
Tested my PO4 this am after my 2nd dose of LaCl3 and it is now .03. That's after 2 diluted doses of LaCl3 at 2.5 ml / L for 150 gallons. I'm still quite impressed. In 3 days it brought my PO4 down to .03 from .49 after 2 doses. I'll keep an eye on it, because I'm sure I'll have some PO4 leaching from my LR, but I don't mind another dose or two. The biopellets and GFO should help as well.
Chris: post a rough cost comparison of each method ;)
 
A Combo would be Best IMO...

A Combo would be Best IMO...

If you'll indulge me, I've been using most of the methods for a little while now, most recently the LaCl3.

Although the carbon dosing method works for some to control PO4, I think it's most effective at dropping NO3. If you feed anywhere close to generously, your PO4 will remain high well after your NO3 has bottomed out at 0ppm. Here's a brief summary:

500 Gallon [Rehabilitation] System:
  • Roughly 8 years old; 6 of which was under-filtered;
  • After 6 years embarked on Biopellets & GFO;
  • Gradually worked my way up to an optimal quantity of BP (appprox. 2.5L) which eventually brought NO3 down from 100ppm + to 0ppm in about 8 months;
  • While using BP I also embarked on an aggressive GFO regimen which was going through about 2.5lbs of GFO every 2 - 3 months. At best I was able to drop PO4 from about 2.0ppm to about 0.35ppm. As soon as the GFO would be exhausted, PO4 would inevitably climb back up toward 0.75 ish (leaching out of rocks; feeding; etc);
  • After spending hundreds of $$ on GFO, I finally managed to rig up a LaCl3 system using a 5 gallon pail as a settling area, with all of the effluent going through a skimmer;
  • After about 2 weeks (and a couple of heavy-handed doses while dialing this thing in), PO4 dropped from 0.75 to 0.02, but has fluctuated between 0.03 - 0.12 over the following month or two while I continued to dial in the drip and throughput; and while GHA and PO4; and cyanobacteria worked their way out of the system...
  • Currently, the system is sucking a 1% dilution of LaCl3:RO/DI through the 5 gal pail and skimmer at a drip rate of apporx 1 drop per 10-15 seconds (24/7) alongside an aquarium water throughput of approx. 20 or so GPH - this seems to be keeping PO4 at 0.03 - 0.07 while GHA & cyano bacteria continue to work their way out, and I'm sure the LR is still leaching quite a bit of its 8 year storage
  • This is my second cyanobacterial bloom on this system. I believe it was triggered by elevated PO4; a lapse in zeobak supplementation; while allowing the system pH to drop down to 7.75/7.90 (as a result of carbon dosing). There is no biotower on the system; the skimmer is well undersized; and there is no refugium... therefore I have to allow the DT drain to splash into the sump, in order to boost pH above 8.1. I've done this following my last water-change, and the pH is now holding at 8.2/8.3... I haven't resumed the zeobak routine fully yet, but am waiting to see if the cyano will run its course by simply raising the pH and blowing it off the rocks every now and again...
  • In all I believe I am going through 1L of BP every 4 months (CAD$90 per 1L SWC Xtreme); and have only used 1/2 of my first (CAD $70 per L) bottle of SeaKlear despite my heavy-handed initiation
  • As for GFO - I was spending about CAD $100 per two months to no permanent avail.

550 Gallon Public Reef (1000g TSV):
  1. 3 year Old System; 8% waterchange 2x per week; huge bio-tower; two refugiums; two large beckett recirc skimmers; very heavily fed;
  2. Aways used GFO at a rate of about 2.5 lbs every 4-5 months;
  3. Embarked on EtOH dosing about a year into the reef's existence at which point NO3 was hovering between 20 - 30ppm;
  4. Evenutally ramped up EtOH to drop NO3 down to 0ppm over the course of about 6-7 months;
  5. Despite EtOH & GFO, PO4 still only reached as low as 0.20 ppm;
  6. Took a break from EtOH due to the development of Cyanobacteria;
  7. After a couple of months, Cyano was resolved by focusing on raising pH back up from 7.8 - 7.9 to 8.05 - 8.15; by raising my carbonate hardness back up from 6.0/6.5 to 7.5/8. I also resumed EtOH dosing and began to supplement with zeobak;
  8. Took a little while but NO3 eventually got back down to 0ppm - at least until the next break from EtOH dosing (can't remember exactly what the reason was for this break); there was also another brief cyano outbreak
  9. Again the focus was to raise pH which had again slipped below 8... no more cyano in display tank, but NO3 is still holding at 10-18ppm and I'm still raising the EtOH dosage to drop back down to 0.
  10. In any event, the point here is that despite spending about CAD$100 per 3-4 months on GFO, the PO4 on this system still never dropped below 0.20 due to the heavy feeding...
  11. Just ordered a dosing pump so that I can setup a LaCl3 dosing system similar to that setup by Mike Cao (August TOTM).

So in summary for two large systems:

GFO is a very expensive option for large systems: approx. $100 per 2 months will not maintain trace levels of PO4 on a well fed system.

Carbon Dosing is very effective for NO3 control but does not effectively deal with PO4 on a well fed system. On a large system you can expect to spend approx. $90 per 4 - 5 months, but will achieve trace levels of NO3, but not PO4.

LaCl3 is extremely effective at achieving trace levels of PO4. on a large system you can expect to spend approx. $70 per 12 - 18 months even though it is heavily fed.

This of course is based only on my opinions generated from first hand observations. Keep in mind that I've only recently embarked on the lanthanum chloride method... but from all indication; I intend to stick with it as a compliment to any form of carbon dosing.


Regards,

Sheldon
 
Chris: post a rough cost comparison of each method ;)

Hi Gary,
I think everyone knows how expensive the GFO can be, if you don't regenerate the GFO, the need for a reactor, etc. Same as biopellets.

A bottle of LaCl3 from SeaKlear is $30 for a 32 oz bottle. I use 2.5 mL of the stuff per dose, so if I dose 1x per week, I'll be using this stuff well into 2030. The 1L of DI water is pennies as well.
 
Well ,I don't agree with the position about PO4 control and carbon dosing. The rlduction in PO4 is significant ,ime.My experience with vodka and vinegar dosing is that imodrate dosing does maintain low PO4(< .07ppm ) in a very heavily fed system all by itself. To keep it under .05ppm a relatively small amount of regenerated gfo is required ( about 3 cups) changed out monthly for teh 600gallons.
The amount of nitrogen taken out via organic carbon dosing exceeds the proportionate amounts to PO4 in inputs because the nitrogen is not only consumed by bacteria but some of it is gassed off as N2 via anaerobic respiration. Significant amounts of phosphate are consumed, however.
Food web contibutions from the bacteria also are arguably a plus .

Don't care for the biopellets because they are carbohydrates which go to sugars and require more equipment than shooting in some vodka and vinegar both of which are simpler chemically than carbohydrates and do not introduce monomers(sugars). Nor do they require the filtration needed with LaCl and they don't leave precipitated PO4 in the tank. The ethanol( vokda )oxidizes to acetic acid( vinegar) .The acetate is useful to corals. There is less of a bacterial cascade and less byproduct than with polymerts( ie pellets)

LaCL works very well for PO4 reduction but desn't help nitrate at all. It is ,nonetheless ,a valuable tool as are the other methods including organic carbon dosing and gfo,imo.
 
tmz, at .05 do you battle algae at all? I am considering trying LaCl but my phosphate reading with my hanna is anywhere from 0 to .08 which doesn't seem high but I fight HA??
 
post a rough cost comparison of each method

For 600 gallons:

Vodka @ $14 for1.75 liters; 0.8cents per ml; daily dos is 26 ml at a cost of 21 cents per day

Vinegar @ $4.59 for 1 gallon( 3,785 ml); 0.12cents per ml; daily dose 64 ml at a a cost of 8cents per day.

Total cost for organic carbon dosing 29 cents per day for 600 gallons

or 0.48cents per gallon / for 40 gallons just about 2 cents per day for vodka and vinegar vs Seaklear at $30 for 946ml ( 1 quart) =3cents pr ml / for 2.5 ml that's 8cents per day

Gfo may be needed with either Lacl or vodka vinegar since both methods are weaker at the low end of the PO4 range. Anyway for fun. U BRS HC GFO @ $125 pr gallon;dosed at 24 ozs for 600 gallons changed once per month = $125 divided by 5.3 doses available in a gallon (128oz divided by dose of 24 ozs) or $23.58 per month/ 79 cents per day without regeneration for 600 gallons or 0.013 cents per gallon of system water . ie 5 cents per day for 40 gallons. Regenerated 10x equals about one ninth of that cost to reflect regeneration costs or 9 cents per day for 600 gallons or .6 cents for 40 gallons.
 
Tracey . No battles; a wisp of it now and then but systems are different. Lacl may not be very effective at low range phosaphate removal as some of it takes up carbonate when PO4 is scarce. Pehaps your rock is leaching some.
 
Thanks for the breakdown Tom. Very good to see the $$ and how it works out per gallon.

My PO4 has crept up to .13 as of yesterday, which I believe is due to the rock leaching out some PO4. I will dose LaCL3 again today to get it back down to .03ish. I imagine that I will need to dose the LaCL3 a couple of times per week until the PO4 stablizes at .03.
 
If it's leaching it may take a few weeks of keeping the waer at near PO4 to use up the PO4 loosely bound to the rock surface .
 
Does anyone know if there is a Rochester area source of Seaklear, yet? Any local LFS stocking the 10 mic bags yet?
 
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local (Roch.) source 10 micron poly... I use 8 x 16" w/steel ring

local (Roch.) source 10 micron poly... I use 8 x 16" w/steel ring

Schwarz, Ralph C & Sons 56 Oxford St. Rochester, NY
 
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