Jonathan,
I am having the same issues that you are having. The electronic solenoid shuts off when the water from the float causes back pressure, but the auto shut off valve doesn't stop the waste water from pouring down the drain. I was told that if you put some kind of "bladder" in line between the clean output of the RODI and the electronic solenoid then that should work. I haven't tried it yet, but the thing to get would be the water tank commonly sold with a household RODI system. I don't know if you can just put a PVC creation inline, if that would work. The water tanks I believe have an expandable bladder in them that causes the pressure, although I could be completely wrong. I have something I am going to try and I will let you know if it does the trick.
Jeff